Carbon Bond-IV Reaction Mechanisms

{ 1}          no2  =  no +  o                     # 1.0         /l1;
{ 2}       o       =  o3                          # 8.383e+04   @-1175;
{ 3}  o3  +   no   =  no2                         # 2.643e+03   @1370;
{ 4}  o   +  no2   =  no                          # 1.375e+04;
{ 5}  o   +  no2   =  no3                         # 2.303e+02   @  -687;
{ 6}  o   +   no   =  no2                         # 3.233e+02   @  -602;
{ 7}  o3  +  no2   =  no3                         # 1.760e+02   @2450;
{ 8}          o3   =  o                           # 1.0000e-03        /l5;
{ 9}          o3   =  o1d                         # 1.0000e-03        /l4;
{10}         o1d   =  o {#1.147e+05 @-390; gery}  #2.864e+10 @-126.;{carter}
{11}  h2o +  o1d   =  2.0*oh       {#3.26; gery}  # 3.25e+05;
{12}  o3  +   oh   =  ho2                         # 2.344e+03   @ 940;
{13}  o3  +  ho2   =  oh                          # 2.100e+01   @ 580;
{14}  no3          = no2 + o                      # 1.0         /l3;
{15}  no3 +  no    =  2.0*no2                     # 1.909e+04   @  -250;
{16}  no3  + no2   =  no + no2                    # 3.660e+01   @1230;
{17}  no3  + no2   =      n2o5                    # 7.849e+02   @  -256;
{18}  n2o5 + h2o   =   2.0*hno3                   # 1.900e-06;
{19}  n2o5         =   no3  +    no2              # 2.110e+16   @10897;
{20}  no  +  no    =   2.0*no2  + 2*ox            # 2.600e-05   @  -530;
{21}  no   + no2 + h2o =   2.000*hono             # 1.600e-11;
{22}  oh   + no    =   hono                       # 6.554e+02   @  -806;
{23}  hono         =   oh    +      no            # 0.171       /l1;
{24}  oh  +  hono  =   no2   +  ox                # 9.770e+03;
{25}  hono + hono  =   no    +      no2    + ox   # 1.500e-05;
{26}  oh   + no2   =   hno3                       # 1.537e+03   @  -713;
{27}  oh   + hno3  =   no3     +   ox             # 7.6         @ -1000;
{28}  ho2  + no    =   oh     +     no2   + ox    # 5.482e+03   @  -240;
{29}  ho2  + no2   =   pna                        # 1.640e+02   @  -749;
{30}  pna          =   ho2      +   no2           # 2.876e+15   @10121;
{31}  oh   + pna   =   no2                        # 1.909e+03   @  -380;
{32}  ho2   +ho2   =   h2o2                       # 8.739e+01   @ -1150;
{33}  ho2 +  ho2 + h2o  =   h2o2                  # 7.690e-10   @ -5800;
{34}  h2o2         =  2*oh                        # 1.0000e-03  /l6;
{35}  oh  +  h2o2  =   ho2                        # 4.720e+03   @ 187;
{36}  oh +   co    =   ho2                        # 322.;
{37}  form + oh    =   ho2     +    co            # 1.500e+04;
{38}  form        =  2*ho2  +       co            # 1.000e-03         /l7;
{39}  form        =   co                          # 1.000e-03         /l8;
{40}  form + o     =   oh        +  ho2   +      co  # 4.302e+04  @1550;
{41}  form  +no3   =   hno3      +  ho2    +     co  # 9.300e-01;
{42}  ald2 + o     =  c2o3    +    oh                # 1.739e+04  @ 986;
{43}  ald2 + oh    =   c2o3                          # 1.037e+04  @  -250;
{44}  ald2 + no3   =   c2o3    +    hno3             # 3.700e+00;
{45}  ald2        =  xo2 + 2*ho2 + co + form         # 1.000e-03      /l9;
{46}  c2o3 + no    =  no2 + xo2 + form + ho2  + ox   # 7.915e+03  @  -250;
{47}  c2o3 + no2   =   pan                           # 1.180e-04  @ -5500;
{48}  pan         =   c2o3 +       no2               # 5.616e+18 @14000;
{49}  c2o3 + c2o3  =  2*xo2 +  2*form + 2*ho2        # 3.700e+03;
{50}  c2o3 + ho2   =  0.79*form + 0.79*xo2 + 0.79*ho2 + 0.79*oh # 9.600e+03;
{51}  oh          =   xo2    +   form  +     ho2     # 7774.  @1815; 
{52}  par  + oh   =  0.87*xo2 + 0.13*xo2n + 0.11*ho2 + 0.11*ald2 +
                    0.76*ror + -0.11*par                        # 1.203e+03;

{53}  ror        =  1.1*ald2 + 0.96*xo2 + 0.94*ho2 + -2.10*par + 0.04*xo2n +  
                    0.020*ror                              # 6.250e+16  @ 8000;

{54}  ror        =   ho2                                   # 9.545e+04;
{55}  ror  + no2  =  ornit                                 # 2.200e+04;
{56}  o    + ole  =  0.63*ald2 + 0.38*ho2  + 0.28*xo2 + 0.3*co  + 0.2*form +
                    0.02*xo2n + 0.22*par +  0.2*oh         # 1.756e+04  @324;
{57}  oh   + ole  =  form + ald2 + xo2 + ho2 + -1*par      # 7.74e+03   @ -504;
{58}  o3   + ole  =  0.5*ald2 + 0.74*form + 0.33*co + 0.44*ho2 +
                   0.22*xo2 + 0.1*oh + -1.00*par           # 2.104e+01  @ 2105;
{59} no3 + ole = 0.91*xo2 + 0.09*xo2n + form + ald2 + -1*par + no2 # 1.135e+01;
{60} o   + eth = form + 0.7*xo2 + co + 1.7*ho2  + 0.3*oh  # 1.540e+04   @ 792;
{61}  oh   + eth  =  xo2 + 1.56*form + ho2 + 0.22*ald2    # 3.000e+03   @  -411;
{62}  o3   + eth  =  form + 0.42*co +  0.12*ho2           # 1.856e+01   @2633;
{63} oh + tol = 0.08*xo2 + 0.36*cres + 0.44*ho2 + 0.56*to2 # 3.106e+03  @  -322;
{64}  to2  + no  = 0.9*no2 + 0.9*ho2 + 0.9*open +0.1*ornit + 0.9*ox # 1.2e+04;
{65}  to2        = cres  +  ho2                                     # 2.5e+02;
{66}  oh   + cres = 0.4*cro + 0.6*xo2 + 0.6*ho2 + 0.3*open          # 6.1e+04;
{67}  no3  + cres = cro   +      hno3                               # 3.25e+04;
{68}  cro  + no2  =   ornit                                         # 2.0e+04;
{69}  open       = c2o3 +   ho2 + co     {94% of mgly prate}   # 0.938e-03 /l15;
{70}  open + oh   = xo2 + 2*co + 2*ho2 + c2o3 + form                # 4.4e+04;
{71}  open + o3   = 0.03*ald2 + 0.62*c2o3 + 0.7*form + 0.03*xo2 +
                 0.69*co + 0.08*oh + 0.76*ho2 + 0.2*mgly    # 8.03e-02  @ 500;
{72}  oh   +xyl   = 0.7*ho2 + 0.5*xo2 + 0.2*cres + 0.8*mgly +
                   1.1*par + 0.3*to2                         # 2.453+04  @ -116;
{73}  oh  + mgly  = xo2  +  c2o3                              # 2.6e+04;
{74}  mgly       = c2o3  + ho2  + co                          # 1.e-03     /l15;
{75}  o  + isop   = 0.6*ho2 + 0.8*ald2 + 0.55*ole + 0.5*xo2 +
                   0.5*co + 0.45*eth  + 0.90*par              # 2.7e+04;
{76}  oh  +  isop  = xo2 + form + 0.67*ho2 + 0.13*xo2n + eth +
             0.4*mgly + 0.2*c2o3 + 0.2*ald2            # 1.42e+05;
{77}  o3  +  isop  =   form  + 0.4*ald2 + 0.55*eth + 0.2*mgly + 0.1*par +
                      0.06*co + 0.44*ho2  + 0.1*oh         # 1.8e-02;
{78}  no3 +  isop  =   xo2n   + ornit                      # 4.7e+02;
{79}  xo2  + no    =   no2       + ox                      # 1.2e+04;
{80}  xo2  + xo2   =                                       # 2.550e+01 @  -1300;
{81}  xo2n + no    =    ornit                              # 1.e+03;
{82}  nr          =   nr                                   # 1.e+00;
{83}  apin        =  7*par + 0.75*ald2 + 0.75*ole           # 1e10;
{84}  unkn        =  7.5*par + 0.875*ald2  + 0.375*ole      # 1e10;
{85} no3          = no                            # 1.0         /l2;
{86}  o  + diene   = 0.6*ho2 + 0.8*ald2 + 0.55*ole + 0.5*xo2 +
                    0.5*co + 0.45*eth  + 0.90*par              # 2.7e+04;

{87}  oh  +  diene   = xo2 + form + 0.67*ho2 + 0.13*xo2n + eth +
                    0.4*mgly + 0.2*c2o3 + 0.2*ald2            # 1.42e+05;

{88}  o3  +  diene  =   form  + 0.4*ald2 + 0.55*eth + 0.2*mgly + 0.1*par +

                      0.06*co + 0.44*ho2  + 0.1*oh         # 1.8e-02;
{89}  no3 +  diene  =   xo2n   + ornit                     # 4.7e+02;